SusChem: An ETP2020 for Innovation and Growth in Europe

SusChem, the European Technology Platform for Sustainable Chemistry, has released a new video describing its new role as an 'ETP2020'. The announcement of SusChem's achievement of ETP2020 status was made on 12 July 2013 and coincided with the publication of a European Commission document on a 'Strategy for European Technology Platforms: ETP 2020'.

ETP2020 organisations will be a valuable tool for Horizon 2020 and the ETP 2020 strategy seeks to maximise the impact of European Technology Platforms (ETPs), such as SusChem, on Europe’s competitiveness and sustainability.

The new SusChem video (below) features contributions from SusChem Chairman Dr Klaus Sommer, Waldemar Kutt from the cabinet of European Commissioner for Research and Innovation Maire Geoghegan-Quinn, and Fernando Moreno, CEO of Solutex and SusChem board member.

The video 'SusChem: An ETP2020 to Promote Innovation and Growth in Europe' describes the important role of Technology Platforms in EU research and innovation strategy and the specific objectives that SusChem has in areas such as resource efficiency, water, critical raw materials, smart cities, key enabling technologies, and education and skills.

The video concludes with discussion of the scale of the opportunity for SusChem to contribute to EU growth and jobs and the added value that SusChem brings to EU and transnational innovation initiatives. Enjoy!



More information
For more information on SusChem activities and how you can participate visit the SusChem website or contact the SusChem secretariat.

CAPITA First Call for Proposals Has Been Launched

CAPITA, a new FP7 ERA-Net project that aims to improve transnational cooperation in applied research in innovative manufacturing, has launched its first call for proposals.

The aim of this call is to fund innovative transnational R&D projects related to Applied Catalysis and Catalytic Reaction Engineering within its thematic priority.The call, titled “Innovative catalysis for the monetization of low value carbon", will be open to any contribution that can bring added value in the fields of:

• Improved use of light alkanes
• Efficiency of CO2 in processes
• Efficient catalytic conversion of biomass into biofuels, platform molecules and fine chemicals
• Sustainable chemical processes.

The call is open to any project which achieves results by relying on the following methodologies:

• Thermal catalytic reactions
• Electro-catalytic reactions
• Photochemical reactions
• Photo-electrochemical reactions

The project deadline to submit an application is the 2nd September 2013.

What is CAPITA?

The FP7 ERA-Net project CAPITA consists currently of programme owners and managers from (regional) ministries, funding agencies and research councils from six European countries. They aim to form an ERA-Net that will help  improve the cooperation and coordination of research activities carried out at national or regional level through:

• the networking of research activities conducted at national or regional level, and
• the mutual opening of national and regional research programmes.

CAPITA’s aim is to establish enduring transnational cooperation in applied research leading to innovative and exploitable manufacturing technology for chemicals, materials, and energy.

By working closely with SusChem and other European Technology Platforms, the new ERA-Net will play a major role in delivering strategic research plans. Collaboration between academia, industry, research organisations and government will be built into its every aspect.

SusChem to Lead “Industry Expert Group on Barriers to Innovation” in EIP Water

SusChem is now leading the newly created “Industry Expert Group on Barriers to Innovation” in the European Innovation Partnership on Water. This group is charged with supporting a task force preparing a diagnosis report on barriers to innovation in the water sector. Composed of selected personnel with years of expertise in the field, the Expert Group will voice the industry’s position and preferences in overcoming the many hurdles impeding innovation in the sector.

The Expert Group is formed by associations and companies with strong stakes in the water sector:  the municipality of Kalundborg in Denmark, Dow Iberica, EuropaBio (EU)/BiosSciences KTN, Abengoa Water, ESTEP, Cefic, Tecnicas Reunidas/ETP SMR, VITO, SusChem Spain, Solutex, TNO, Arkema, Cyprus Universtity of Technology, Kemira, Dechema, Copenhagen Capacity, WssTP and SusChem.

The aim of the report is to present a real diagnosis of the current European situation and to suggest actions to be taken to accelerate innovation in water. The support of the Expert Group from the industrial sector ensures that the final report will take account of every obstacle to innovation so that proper solutions can be adopted.

SusChem’s role in the Expert Group confirms its strong commitment to contribute to innovation in water – a key area for chemistry in Europe in the years to come.

What is the EIP on Water?

European Innovation Partnerships aim to speed up innovations that contribute to solving societal challenges, enhance Europe's competitiveness and create jobs and growth.
As part of the Partnerships, the EIP Water aims to

·         speed up development of water innovation

·         contribute to sustainable growth and employment

·         stimulate uptake of water innovations by market and society

The EIP Water will develop tools to support water-related innovation. These tools will not necessarily be linked to the priorities of the EIP Water, but they will also be available to any party dealing with water and innovation.

F3 Factory Project: The Case Studies

The SusChem-inspired F³ Factory was a FP7 funded collaborative research project on fast, flexible, modular process technology for the future chemical industry. At the heart of the project were seven industrial case studies that covered a range of processes challenges. Details of these case studies have now been published.

Launched in 2009 the €30 million F³ Factory project was a major public-private sector initiative under FP7 that sought to define and demonstrate a new paradigm in modular sustainable chemical production technology.

At the project’s final presentations to the SusChem Stakeholder event on 14 May SusChem Chairman Dr Klaus Sommer said: "It was a privilege and an honour to be involved with this project that has not only produced excellent new scientific knowledge, but also shown how to bridge the innovation gap and with a consortium including many major companies working very effectively together."

The fruits of this ground-breaking project will feed into future major SusChem programmes such as the SPIRE and BRIDGE 2020 public-private initiatives during Horizon 2020.

Case studies
Seven major European Chemical Companies (Arkema, Astra Zeneca, BASF, Bayer, Evonik, Procter and Gamble and Rhodia-Solvay) worked collaboratively in the project demonstrating that large scale, pre-competitive collaborative research is both manageable and potentially highly fruitful.

The case studies spanned a broad range of process industry sectors including pharmaceuticals, chemical intermediates, specialty polymers and consumer products and aimed to:

·                     demonstrate the F³ Factory modular concept at industrial scale for commercial applications 

·                     realise an open access backbone plant for modular continuous production 

·                     validate new intensified and simplified continuous processes 

·                     design and validate new/enhanced reactor technologies 

·                     establish of design guidelines and standards for modular, container-based production units.

The establishment of standardised modular equipment was a significant achievement for the project. The smallest interchangeable unit is the process equipment assembly (PEA) a number of which would be integrated within the standard process equipment container (PEC): a standard EU 20-foot ISO norm container (see example below).

The seven case studies are:

1. Water Soluble Speciality Polymers
2. Continuous Processing for Pharmaceuticals
3. Continuous Production of Chemical Intermediates
4. High-Volume, Biomass-based Intermediate Chemicals
5. Active Pharmaceutical Intermediates
6. Intensified Reaction Technology for Surfactants
7. Highly Viscous Polymers

Click on the links to find out more about each case study.

Overall results

For business the F³ Factory project demonstrated increased investment flexibility, potential capital expenditure reduction up to 40%, potential operating expenditure reduction up to 20% and the potential to deliver a much faster 'time to market' for new products - a major competitive advantage.

The potential impact of the project could be very significant. Just looking at capital expenditure, it is estimated that such expenditure in the chemical industry ‘in western Europe’ (EU-15 plus Norway and Switzerland) was ~€ 39 billion in 2011.

If the F³ Factory could save up to 40% on capital expenditure for projects that equates to a maximum annual saving of €15.6 billion. Even at a conservative 10% take-up of the project concepts this still represents a potential annual saving of more than € 1.5 billion in Europe in the chemical industry alone.

From an environmental and resource efficiency point of view the project has demonstrated reduced energy consumption up to 30%, solvent reduction up to 100%, footprint reduction up to 50% and the potential to reduce or eliminate transportation by enabling local or point of use production.

In addition the project has successfully validated new intensified and simplified continuous processes that have demonstrated process intensification up to a factor of 500, increased space-time-yield up to a factor greater than 100, increased capacity greater than 20%, increased production yield greater than 20%, reduced equipment need of more than 60%, reduction of reaction/processing time by a factor of 10 and through these simplified processes achieved reduced reaction and processing steps of up to 30%.

And finally, the project has realised an innovative open access backbone plant (INVITE) facility for modular continuous production – a resource for European process development that will have continuing value for many years to come.

F3 Factory Case Study: Highly Viscous Polymers

BASF and Bayer Technology Services (BTS) collaborated to demonstrate the F³ Factory concept for multi-product, small-to-medium scale production of high viscous polymers in a solvent-free manufacturing process. Supported by academic input from the Technical University of Eindhoven and the University of Paderborn, this case study featured the development and demonstration of a new flexible, reactor technology within a modular, continuous production unit.

The transfer of multi-product batch polymerisation of high temperature thermoplastics in organic solvent to a solvent-free process is a challenging task and has so far prevented producers from developing solvent-free processes.

Without reducing viscosity by applying very large amounts of solvents, “difficult processes” like solvent-free polymerisation cannot be carried out in standard mixers. The focus of this F³ Factory case study therefore concentrated on the development of intensified, high-strength mixing equipment. To succeed this approach needed to guarantee material integrity and enable effective supplementary mixing as well as devolatilisation and solidification. Performance at long residence times in continuous mode also needed to be assured.

New reactor technology

A new twin-shaft, high-torque kneader reactor developed by Buss-SMS-Canzler (pictured below) was shown to meet the key requirements of strength and operational flexibility and led to a step-change improvement in viscosity handling up to 10 000 Pascal seconds.

Modular construction and many standardised parts also allow for flexible adaptation to different products and processes, with the ability to switch rapidly between different mixing rotor assemblies.

Collaboration key to success

To realise the full potential of this intensified kneader reactor, its complex geometry required focus on several key durability issues. Their examination has been a classic model of F³ Factory project partnerships.

The University of Paderborn (UPB) investigated the mechanical integrity; modelling of unit processes; radial and axial mixing; micro/macro mixing and axial dispersion. Investigations confirmed the ecological and economic advantages of the kneader from its fast radial mixing and minor back mixing plus well-developed devolatilisation based on reactor partial-fill operation.

Numerical simulations using CFD analysis were performed by Technical University Eindhoven to calculate the velocity and pressure fields within the kneaded material, leading to rotor strength and fatigue computations by Buss-SMS-Cransler (SMS). Online measurement techniques for the high-torque kneaders were then developed by BASF, with technology transfer to UPB and SMS.

BTS derived a mass-balance for the intensified kneader reactor design, providing the liquid filling level as a function of viscosity, throughput and rotational speed. Following validation of the new reactor technology at lab-scale and successful polymerisation trials, the modular plant concept was designed by BTS and demonstrated successfully at the INVITE facility.

Solvent-free, high viscous polymers

Excellent progress on the integration of process and equipment design enabled illustration of the plant concept and contributed to the design and construction of a pilot facility at BASF’s site in Ludwigshafen. The new solvent-free process was subsequently validated with a continuous lab-scale kneader reactor.

The intensified process was then transferred to the F³ Factory modular, continuous plant concept with design of a demonstrator Process Equipment Container and respective Process Equipment Assemblies.

By eliminating the use of solvents, the process has been intensified significantly. It has reduced complexity, energy consumption and facilitated the successful transfer from batch to continuous polymerisation.

The case study was demonstrated successfully at the INVITE facility in Leverkusen, over an extended processing time, confirming both the strength and integrity of the kneader reactor.

In addition to the technological advancement achieved in this project, the transfer from batch to continuous of a new solvent-free polymerisation process has demonstrated both cost (30% reduction in energy demand) and environmental benefits (100% solvent reduction) for the continuous production of high viscous polymers.

More information

For more information visit the F3 Factory Project website or contact Dr. Achim Stammer at BASF.

F3 Factory Case Study: Intensified Reaction Technology for Surfactants

Achieving step-change process intensification in the production of anionic surfactants was the primary goal of the Procter & Gamble (P&G) industrial case study. Working with project partners the Institute of Chemical Process Fundamentals (ICPF), Britest and Karlsruhe Institute of Technology (KIT), the project focused on the intensification of two key reactions stages (S0₂ oxidation and sulphonation) using novel reaction technology and modelling of the economic viability of the concepts in the latter stage of the project.

As one of the world’s leading consumer products businesses P&G is one of the largest global manufacturers of surfactants. With no major developments in surfactants production technology for decades, potential gains from the novel F³ Factory approach could be significant.

The current business model is to produce bulk surfactants at large-scale, centralised locations and then ship to finishing sites. A step change in the base technology could lead to differentiated supply chains including more distributed, less transport-intensive scenarios and reduced business risk.

In changing the operating strategy for anionic surfactants, P&G is seeking to unlock the benefits of flexibility, agility and long-term sustainability.

Technological developments

Process intensification is seen as the main lever available to progress the supply chain to a more sustainable and lower cost model. Concentrating on the two unit operations is essential to an overall step change; therefore, the project has focused on SO₂ oxidation and sulphonation.

The size and inertia of current SO₂ oxidation towers negatively impacts on the whole plant agility. In addition, due to limited use of intensification, sulphonation forces the dilution of SO₃ with large amounts of air. This markedly increases the plant’s capital, volumetric and environmental footprint.

Proof-of-concept work focused on:

• obtaining targeted lab scale information on oxidation of SO₂ in micro-channel settings
• identifying technical intensification strategies for sulphonation
• development of two new reactor designs

The project team investigated the concept of a microstructured reactor with an adiabatic section at the beginning of the reactor beginning and one cooling section at the rear of the reactor. Based on experimental measurements of kinetics, simulations of the reaction kinetics and heat transfer; a new reactor design with two parallel microstructured reactors was developed (see below).

The project team also investigated the concept of a new intensified device for sulphonation. The experimental study focused on hydrodynamic behaviour of lab scale equipment in a wide range of operating conditions. The pressure drop and heat transfer coefficient were determined and an adequate correlation developed.

The sulphonation process on the lab scale reactor prototypes, that were designed and manufactured at ICPF in Prague, was tested during the demonstration phase of the project in P&G’s pilot plant facility in Brussels. This intensified sulphonation process developed new learning, which may help in further intensifying current reaction systems.

What, when, where

The F³ Factory programme has been a unique collaborative endeavour that could stimulate the transition to a new business model for the whole chemical sector.  In this new model flexible, modular, continuous and intensified technologies are used to meet the challenge of producing “what’s needed, when needed, where needed” therefore minimising the environmental and economic footprint and reducing business risk.

For the P&G case study, intensification of two key reactions stages (S0₂ oxidation and sulphonation) in the production of anionic surfactants using novel reaction technology was largely proven at the lab scale. The challenge going forward will be to prove the economic viability of modular production technologies on highly optimised, large scale surfactants manufacture.

More information

For more information visit the F3 Factory Project website or contact Diederik Vanhoutte at P&G.

F3 Factory Case Study: Active Pharmaceutical Intermediates

As a F³ Factory Case Study Bayer Technology Services (BTS) investigated the transfer of a multi-step synthetic batch process for pharmaceutical intermediates to a fully continuous manufacturing process in a modular, flexible infrastructure including downstream processing. Working with other industrial and academic partners, Ehrfeld, Britest, TU Dortmund, University of Paderborn, Ruhr-University Bochum and RWTH Aachen, this case study successfully validated and demonstrated a major paradigm shift towards modular, continuous processing of active pharmaceutical intermediates.

The BTS project sought to assess the potential to replicate the cost, quality and efficiency benefits of large-scale continuous production in modular, flexible, small-scale container-based production units. In demonstrating a sequence of synthesis stages in a container environment, BTS also integrated a range of innovative, highly efficient process equipment solutions.

Starting from a five stage reaction sequence with intermediate isolation, key stages of the project included:

• chemical redesign against the paradigm shift of continuous processing
• simultaneous chemical and continuous process development
• integration of reaction and separation steps in the container unit  
• demonstration of the new process in the modular F³ Factory design

Cost and efficiency

Research and development activity in the first phase of the project demonstrated significant savings and efficiency gains with cross-project benefits for the wider F³ Factory programme.

Transfer of the chemical synthesis to an intensified fully continuous process led to a significant reduction in processing steps, reaction time and the amount of solvent used.

BTS operated the process sequence successfully for several days at bench scale, confirming the assumed benefits of the F³ Factory approach in terms of impact on footprint, resource consumption, continuous monitoring and process operability. Key benefits identified to date include:

• reduction in starting material costs (average 15% depending on transformations involved)
• increase in space time yield (up by factors >100)
• significant reduction in both reaction and processing time
• simplified work up processes due to elimination of intermediate isolation and purification stages
• unification of solvents and reduction in consumables
• reduction in equipment size
• reduction in design and installation costs (up to 30% depending on transformations involved)
• reduction in apparatus cost (approximately. 30% depending on intensification of the specific modules)

Modular, flexible production

This was the first industrial case study to be demonstrated in the INVITE backbone facility (see above), and therefore the BTS project led the way in establishing standards for process equipment assemblies (PEAs), the Process Equipment Container (PEC) and its integration with the backbone infrastructure services at INVITE.

To achieve maximum flexibility the standardised and scalable equipment used for the development and production phases enabled a fast and robust transfer from research to production in line with the development time line and with minimal effort.

Modular PECs can provide the required production capacity throughout the full product life-cycle. In addition, standardised chemical and physical processing PEA units can allow faster implementation of new manufacturing strategies in the highly regulated environment of pharmaceutical production.

In the latter stages of the project, BTS successfully demonstrated synthesis steps 1 and 2 in the case study’s PEC at the INVITE backbone facility.

The technological and economic benefits demonstrated through this case study provide a platform for the introduction of new technologies, production concepts and process equipment solutions for the European pharmaceutical manufacturing sector.

More information

For more information visit the F3 Factory Project website.